Probing analysis of Cu-doping on the structural, optical, morphological and magnetic properties of hematite nanoparticles and their antibacterial activity

Abstract

The present study describes the synthesis of pure and Cu doped α-Fe2O3nanoparticles (with various concentrations of Copper 1, 3, 6, and 9 wt%) by conventional chemical precipitation technique and examines their structural, morphological, optical, magnetic, and antibacterial capabilities. The XRD pattern of pure and Cu-doped α-Fe2O3 nanoparticles exhibit rhombohedral structure and the estimated crystalline sizes were ranged from 39 to 58 nm. It is discovered that the estimated density dislocations linked to the agglomeration/cluster formations diminish when interstitial vacancies are filled with copper. The obtained bandgap from Tauc’s plot, 2.07 eV of pure α-Fe2O3 is found to less than Cu doped α-Fe2O3 nanoparticles (2.9–3.4 eV), due to the structural changes and the tailing of localised states into deep bandgap energy levels. The intense blue emission bands (410–490 nm) arised due to the movement of trapped electrons from the donor level to the valance band and broad green emission bands (522–560 nm) are due to deep level CuO defect to the Fe2O3. The fundamental stretching of Fe-O vibrations and the presence of Cu in prepared samples were identified in FTIR and Raman spectra. SEM micrograph shows the uniform distribution of spherical nanoparticles with size ranged from 39 to 61 nm, which is in good accord with XRD studies. Further, the magnetic characteristics of the pure and Cu-doped α-Fe2O3 samples were assessed using a vibrating sample magnetometer (VSM); the ensuing hysteresis loop of the Cu-doped α-Fe2O3 displays weaker ferromagnetic behaviour. In the present investigations, the disc diffusion technique has been used to examine the antibacterial activity. Thus, the results of antibacterial activities demonstrated that at concentrations of 200 and 500 μg/ml of pure and Cu-doped α-Fe2O3 NPs, the highest zone of inhibition was found against gram (+ve) positive bacteria and was followed by the gram (–ve) negative bacteria’s.