Abstract
1. A nonadditive character is postulated for the change in energy of van der Waals interaction for members of a homologous series of organic compounds. 2. An equation is proposed, taking into account the deviation of free energy from the additivity principle, and making it possible to calculate the retention parameters of homologs, beginning with the first member, in gas and liquid chromatography, including thin-layer chromatography. 3. On the basis of the results obtained, the equation can be considered as universal and can be recommended for use in calculating parameters describing the behavior of homologs of organic substances in liquid-gas, solid-gas, and liquid-liquid systems in which the interaction is due to van der Waals forces.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
