Abstract
Abstract The rate of vinyl chloride polymerization initiated by doubly labeled benzoyl peroxide ('H in the phenyl ring and 14C in the carboxyl group) in dichloroethane solution was measured by a dilatometric method. The relative significance of primary radical termination in polymerization is examined by kinetic analysis of the polymerization rate data and analysis of the polymer samples recovered at 10% conversion for combined initiator fragments.
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Schedule a callMore From: Journal of Macromolecular Science: Part A - Chemistry
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