Abstract

Transparent nano- coating was prepared by Sol-Gel method from titanium dioxide TiO2 which has the ability to self-cleaning coating used for hospitals, laboratories, and places requiring permanent sterilization. Three primary colors are selected (red, blue, and yellow) as preliminary study to the effect of these colors on the nano-coating. Three traditional oil paints color were used as base, then coated by a layer of TiO2-Sol and deposited on the paints. The optical properties of TiO2-Sol were measured; the maximum absorption wavelength at (λmax=387 nm), the refractive index (n=1.4423) and the energy band gap (Eg=3.2 eV). The structure properties found by X-ray diffraction of TiO2-Sol illustrated that TiO2-Sol is polycrystalline nanoparticle have anatase phase also the morphological properties measured by Scanning Electron Microscopy (SEM) obetained the average grain size of TiO2-Sol was (50.427 nm). Self-cleaning properties measured by tensiometer dives. The best color gave the highest response to self-cleaning is the yellow color where the contact angle before exposure to UV ( = 101.47º ,at t = 0 min) and after exposure over time ( = 1.75º ,at t = 50 min), thus the water sheet of the surface and remove all contaminants.

Highlights

  • Self-cleaning paint has the ability to clean itself

  • Three primary colors were used as a paint and developed to self-cleaning paints by coating the paint surface in TiO2-Sol

  • Self-cleaning properties measured by contact angle which determine the best paint color

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Summary

Introduction

Self-cleaning paint has the ability to clean itself. The phenomenon of self-cleaning is taken from lotus flower which always seen clean even if its grows in muddy medium 1. The self-cleaning depend on: surface roughness of TiO2 photocatalysis, chemical composition of the surface and dirt particle adhesion 2. TiO2 is widely used as a photocatalyst, De Jesus et al in 2015 worked on TiO2/SiO2 composites films compared with pure TiO2 films in relation to adhesion, hydrophilicity and transparency. Both films have been deposited over low iron float glass substrates by sol-gel dip-coating method and different calcination temperatures 5 . Both films have been deposited over low iron float glass substrates by sol-gel dip-coating method and different calcination temperatures 5 . Sangchay, 2016 prepared TiO2/SnO2 thin films by the sol-gel method

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