Abstract

The rich phenomena in the FeSe and related compounds have attracted great interests as it provides fertile material to gain further insight into the mechanism of high temperature superconductivity. A natural follow-up work was to look into the possibility of superconductivity in MnSe. We demonstrated in this work that high pressure can effectively suppress the complex magnetic characters of MnSe, and induce superconductivity with Tc ~ 5 K at pressure ~12 GPa confirmed by both magnetic and resistive measurements. The highest Tc is ~ 9 K (magnetic result) at ~35 GPa. Our observations suggest the observed superconductivity may closely relate to the pressure-induced structural change. However, the interface between the metallic and insulating boundaries may also play an important role to the pressure induced superconductivity in MnSe.

Highlights

  • The rich phenomena in the FeSe and related compounds have attracted great interests as it provides fertile material to gain further insight into the mechanism of high temperature superconductivity

  • An abrupt drop in resistivity at room temperature (RT) was observed at ~10 GPa, and a second resistivity drop appears at pressure ~16 GPa, at which the sample changes to metallic behavior

  • The partial cubic-to-hexagonal transformation at 12 GPa could be similar to the low-temperature stress-induced transformation of 30% cubic-to-hexagonal structure at ambient condition, which has been extensively investigated and is understood to be the source for anomalous magnetic observed in MnSe at ambient condition[31]

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Summary

Introduction

The rich phenomena in the FeSe and related compounds have attracted great interests as it provides fertile material to gain further insight into the mechanism of high temperature superconductivity. The parent compounds of FeAs-based materials exhibit structural transitions from a high-temperature tetragonal phase to a low-temperature orthorhombic phase, which accompanies with an antiferromagnetic (AFM) order[12,13]. Upon doping, both the orthorhombic structure and the AFM phase are suppressed and superconductivity is induced. A natural follow-up work was to look into the substitution effects of Fe by other transition metals on superconductivity of

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