Abstract
Abstract Polymers have large bulk compressibility in the molten state /1/ and their rheological properties are largely affected by pressure applied in polymer processing. The volumetric strain induced by pressure consists of instantaneous and retarded elastic strains, both of which are proportional to pressure, and recover reversibly when pressure is removed. In many crystalline polymers, as observed by B. Maxwell for polyethylene, retarded elastic strain is large, and due mostly to pressure crystallization. This paper describes results of experimental studies relating pressure effects on rheological properties of melt polymers with polymer processing and bulk properties of products. The following items are discussed: pressure induced shear stress, analysis of local deformation pattern, critical shear stress for melt flow fracture, relationship between power law index and bulk compressibility, effects of hydrostatic pressure on melt flow behavior, pressure efficiency of injection molding, jetting phenomena, shrinkage in injection moldings, residual strain, and super-high-pressure injection molding process.
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