Abstract

The partition functions for molecular hydrogen, with an estimate of pressure dependence included, have been calculated, using extension of Heitler-London theory to three electron system. These partition functions have been used to evaluate the equilibrium constants and internal energies for H 2 as a function of temperature and pressure. Tables of partition functions, equilibrium constants and internal energies have been given for T= I 000 ° to 15 000 ° K and for pressures as high as 7.7 × 10 9 dyn/cm 2 .

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