Abstract
The pressure dependence of the infrared-active optical phonon mode (νTO1) in alkaline-earth fluorides has been determined up to 45 kbar. The dependence is found to be less than the Raman-active optical phonon mode. The pressure dependence of the νTO1 mode is observed to decrease in the order CaF2>SrF2>BaF2, while the Raman mode remains rather constant with pressure. Grüneisen parameters have been determined and are compared with those obtained for AB-type crystals.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
