Abstract
Abstract The hysteresis loops of the spin transition crystalline powder Fe(btr)2(NCS)2·H2O, pure or diluted in a Ni-homologue, have been recorded as a function of temperature and pressure. The phase diagrams in p, T axes have been determined. Pressure hysteresis loops, at constant temperature, have been obtained. A pressure-induced structural change is inferred from the data of the pure compound. The possible thermal quenching of the high-pressure structural phase is evidenced. A relationship between the shapes of the temperature and pressure loops is established.
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More From: Comptes Rendus de l'Académie des Sciences - Series IIC - Chemistry
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