Pressure and temperature effects on the hydrogenation of coal-derived asphaltene

Abstract

Pressure and temperature effects on hydrogenation reactions were examined using coal-derived asphaltene at 390,420 and 450 °C, under 3 and 10 MPa of hydrogen partial pressure. Higher conversion was obtained at higher reaction temperatures. Benzene-insoluble material (Bl) was formed at higher temperatures especially at low hydrogen pressure, this Bl being one-third of the reaction product at 450 °C. From structural analysis of unreacted asphaltenes and product oils, at 390 °C, it was concluded that smaller molecular components convert to oil initially and the larger molecules remain as unreacted asphaltene. Under higher hydrogen pressure for all temperatures carbon aromaticity ( f a ) and number of aromatic ring per structural unit ( R aus ) in unreacted asphaltenes were lower than those under lower hydrogen pressure suggesting that hydrogenation of the aromatic nucleus was promoted by higher pressure. At lower hydrogen pressure, R aus for asphaltenes at higher temperature is larger than that at lower temperature. This suggests that at lower hydrogen pressure, dehydrogenation or condensation reactions occur more easily. A large effect at higher hydrogen pressure was a reduction in the extent of condensation reactions. Higher reaction temperatures contribute to splitting of bridged linkages so reducing molecular size and degree of aromatization.