Preparing high strength cementitious materials with high proportion of steel slag through reverse filling approach

Abstract

Steel slag is an industrial solid waste with latent hydration nature, possessing a high potential use in cement and concrete but has not been fully utilized yet. This study reveals an implication approach based on dense packing to achieve high utilization efficiency of both steel slag and cement. Steel slag-based reverse filling approach utilizes higher volume of relatively coarser steel slag particles as micro fillers and a smaller quantity of fine cement grains as the major binding component. Thus, giving an initial compact packing structure and an enhanced strength of the resulting materials. Based on the packing density of various mixes, steel slag-based reverse filling cementitious materials are formulated. Early age hydration kinetics, fluidity of fresh pastes, and properties including mechanical strength and water absorption are further investigated on paste specimens. Results indicated that a maximum packing density of 0.6956 was attained for the blend containing 85 % steel slag with 15 % superfine Portland cement. The compressive strength of formulated mixes reached 96.4 MPa, 105.6 MPa and 123.8 MPa at 180 days for pastes containing 15 %, 25 % and 35 % of superfine Portland cement, respectively. The addition of appropriate amount of gypsum can enhance long-term strength by 8 ∼ 18 MPa through improving the early-age hydration kinetics of the steel slag based cementitious systems. The findings of this research help to valorize steel slag utilization in cement-based materials without sacrificing mechanical property and durability.