Preparation, thermal expansion, high pressure and high temperature behavior of Al2(WO4)3

Abstract

The titled compound Al2(WO4)3 was synthesized by a conventional solid state reaction and characterized by powder XRD. It crystallizes in an orthorhombic (Pbcn, No. 60) lattice, with unit cell parameters as 12.582(2), 9.051(1), 9.128(2) A, and V = 1039.5(3) (A)3. The compound was found to show negative thermal expansion (NTE) behavior in the temperature range of 25 to 850°C. The average linear NTE coefficient (α1), in this temperature range, was −1.5 × 10−6 K−1. The effect of pressure at ambient temperature, was studied by a Bridgman Anvil (BA) apparatus, to reveal that there is no irreversible phase transition up to 8 GPa. The effect of high pressure and high temperature on this compound was studied by a Toroid Anvil (TA) apparatus. This compound has a limited stability under high pressure and temperature, as it undergoes a decomposition to AlWO4 and WO3−x with a partial oxygen loss. As an off-shoot of this work, certain new modifications of WO3−x under pressure and temperature were observed, viz., monoclinic, tetragonal and an orthorhombic modifications at 5 GPa/1400°C, 3 GPa/900°C and 1.8 GPa/1030°C, respectively. The detailed XRD studies of the products are presented here.