Abstract
A series of (β-diketonate)Cu(PMe 3), where β-diketonate = acetylacetonate (acac) ( 1), trifluoroacetylacetonate ( 2) and hexafluoroacetylacetonate ( 3), compounds have been prepared by the reaction of β-diketones with (η 5-C 5H 5)CuPMe 3. A single crystal X-ray diffraction study of (tfa)CuPMe 3 reveals that it is monomeric in the solid state with a trigonal planar copper coordination environment. All three new compounds are volatile and soluble in hydrocarbon solvents.
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