Abstract
The synthesis of tricarbonyl(η6-pyridine)chromium(0) complexes is accomplished via complexation of 2-silylpyridines with subsequent fluoride ion-mediated desilylation under mild conditions. The tricarbonylchromium(0) complexes of pyridine, 2-methylpyridine, 3-methylpyridine, 2-ethylpyridine, 2-(but-3-enyl)pyridine and 2-(6-trimethylsilylpyridyl)-1,3-dioxolane are prepared. Deprotonation (lithium diisopropylamide) and methylation (methyl iodide) of tricarbonyl(η6-pyridine) chromium (0) converts it cleanly into tricarbonyl(η6-2-methylpyridine)chromium (o).
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
