Abstract
Reaction of tricarbonyl (η 4 -vinyl ketone) iron (0) complexes (CO) 3 (PhCH=CHC(R)=O) Fe(0) (R=Me, Bu n , Bu t , Ph) with organolithium reagents under an atmosphere of carbon monoxide gave products that were identified as tricarbonyl «(η 4 -vinylketene)» iron (0) complexes (CO) 3 (PhCH=CHC(R)=C=O) Fe(0)
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