Preparation of TiO2-Nanorods Supported Pd Catalyst and Its Electrocatalytic Oxidation on Formic Acid

Abstract

TiO 2 nanorods (TiO2-R) and irregular TiO2 (TiO2-I) with anatase phase structure are synthesized by hydrothermal synthesis and inorganic sol gel method, respectively. Using as-prepared TiO2 as support, Pd/TiO2 catalysts are prepared by using sodium ethylenediamine tetracetate (EDTA) as complexing agent and NaBH4 as reductant. The studies of transmission electron microscopy (TEM) and X-ray diffraction (XRD) reveal that the average particle size of Pd/TiO2-R catalyst is very similar to that of Pd/TiO2-I catalyst. Cyclic voltammetry measurements show that the peak current of formic acid oxidation at Pd/TiO2-R catalyst increases by 70%. Chronoamperometric measurements indicate that the current density at the Pd/TiO2-R catalyst electrode at 3000 s is almost 16 times larger than that at the Pd/TiO2-I catalyst electrode. These electrochemical experiments show that the electrocatalytic activity and long-term operation stability of Pd/TiO2-R catalyst are much better than that of Pd/TiO2-I catalyst for formic acid oxidation in acidic media, indicating that TiO2 nanorods support material can effectively promote the electrocatalytic activity and sta- bility of Pd catalyst for formic acid electrooxidation. Likely, TiO2 nanorods possess good electronic conduc- tivity and abundant surface oxygen-containing groups, which improve the electrocatalytic activity and the anti-poisoned performance of Pd catalyst for the formic acid electrooxidation. Thus, TiO2 nanorods with