Preparation of TiO2 composite photocatalyst using amorphous SiO2 microspheres loaded with spent SCR catalysts

Abstract

The products of S-SCR grinding and alkali treatment (S-SCR-T, primarily consisting of anatase TiO2 with a size less than 20 nm) were utilized as photocatalysts, while SiO2 microspheres (MS-SiO2) were used as carriers. A TiO2 composite photocatalyst (M-Si/SR-Ti) was prepared by wet mechanical grinding. The results demonstrate that in M-Si/SR-Ti, S-SCR-T was uniformly loaded on the MS-SiO2 surface in a well-dispersed state and firmly bonded at the interface with Si–O–Ti bonds. M-Si/SR-Ti prepared under optimized conditions exhibited excellent photocatalytic degradation and recycling properties for methyl orange. The degradation rate of methyl orange solution at 10 ppm for 60 min under UV irradiation was 97%, which was comparable to that of S-SCR-T, and remained unchanged after four cycles of recycling. Compared with S-SCR-T, M-Si/SR-Ti exhibited significantly improved settlement recovery performance in water. The loading of S-SCR-T on the MS-SiO2 surface, which increased the exposure of the nano-TiO2 active site and decreased the energy gap, was the mechanism responsible for improving the photocatalytic performance of M-Si/SR-Ti. This study positively impacted the effort to efficiently utilize and increase the value of S-SCR and reduce the cost of the photocatalyst.