Preparation of the Temperature-Responsive Superhydrophobic Paper with High Stability.

Abstract

In this paper, a method for preparing a high-stability superhydrophobic paper with temperature-induced wettability transition is proposed. First, a temperature-responsive superhydrophobic triblock polymer PHFMA–PTSPM–PNIPAAm was prepared by one-step polymerization of TSPM, HFMA, and NIPAAm in a mass ratio of 0.3:0.3:0.3, then a superhydrophobic paper with a good temperature response was successfully prepared by grafting amino-modified SiO2 with the polymer to modify the surface of the paper. A further study found that when the mass ratio of amino-modified SiO2 to polymer is 0.2, the coating has good superhydrophobicity and transparency. What is more, the prepared modified paper is in a superhydrophobic state when the temperature is higher than 32 °C, and is in a superhydrophilic state when it is lower than 32 °C, which can realize free conversion between superhydrophobic and superhydrophilic states. In addition, the superhydrophobic paper prepared by this method not only has high oil–water separation efficiency, and the superhydrophobic coating shows good stability and transparency, but also has low requirements of environmental conditions for preparation, relatively simple preparation process, and strong repeatability, and it has a very broad application prospect.