Preparation of spherical and cubic Fe55Co45 microstructures for studying the role of particle morphology in magnetorheological suspensions

Abstract

Cubic and spherical Fe55Co45 alloyed microstructures were synthesized by borohydride reduction from aqueous solutions of metallic precursors, using stabilizers and polymer. Monosodium citrate, sodium acetate and PEG 6000 were utilized as electrostatic stabilizers and polymeric surface modifier. Suitable reaction conditions were maintained for synthesis of predominantly larger particles (0.7µm to 1.2µm), that facilitates use in magnetorheological fluids. Surface morphological studies by scanning electron microscopy revealed well shaped cubic and spherical geometry for the citrate and polymer-stabilized Fe55Co45 alloys, while the alloy compositions remained nearly the same for both. X-ray diffractions of the as-prepared and annealed samples under various temperatures showed high degree of crystallinity with increasing temperatures. Studies of D.C. magnetization of the systems reveal that the particles have a core–shell structure, with inner magnetic core having a diameter around 30nm with a log-normal distribution. Magnetorheological studies were performed with 8vol% suspensions of as-synthesized particles dispersed in silicone oil (viscosity 30mPas at 25°C) under different magnetic fields. Detailed studies of the magnetorheological properties were studied on these systems for practical use.