Preparation of polystyrene and silane-modified nano-silica superhydrophobic and superoleophilic three-dimensional composite fiber membranes for efficient oil absorption and oil-water separation

Abstract

Oily solid waste and wastewater are two kinds of contaminants that seriously endanger the environment and the general public. Recently, superhydrophobic and superoleophilic materials have attracted extensive attention owing to their exceptional oil-water separation capabilities. In this study, we demonstrated a simple, low-cost, and high-economic efficiency method to prepare nanosilica (SiO2) from dye diatomite filter aid waste (DDW) and silanize it with octadecyltrichlorosilane (OTS) to form hydrophobic nanosilica (hSiO2) by solution impregnation. Polystyrene/hydrophobic nanosilica (PS/hSiO2) composite fiber membranes with a rough surface and low surface energy were prepared by electrospinning. The prepared PS/hSiO2 water contact angle can reach 166.6°, showing superhydrophobicity and excellent adsorption capacity for various common oils. The maximum oil absorption capacity for transformer oil can reach 136.4 g/g. Importantly, the oil absorption process of the nanocomposite is selective, fast, and efficient, and it can be used for the purification of oil-contaminated water. In addition, it also demonstrates remarkable durability and stability in strong acid and alkali solutions. This strategy of making oil-water separation materials from solid waste may offer a straightforward, cost-effective, and environmentally sustainable option for the treatment of solid waste, industrial oil wastewater treatment, and marine oil spill cleanup.