Abstract
AbstractSeveral new phenylcarbamate derivatives of cellulose and amylose having fluoro and methyl groups or 4‐trimethylsilyl substituent on the phenyl groups were prepared and their chiral recognition abilities as chiral stationary phases for HPLC were evaluated. These derivatives are soluble in chloroform and exhibit chiral discrimination in 1H NMR spectroscopy. Based on the above results and molecular mechanics calculation of interaction energies between the derivatives and enantiomers, the mechanism of chiral discrimination is discussed.
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