Abstract
Composites based on pure gypsum and polyester–styrene resin have been prepared using various doses of gamma radiation. Some physical properties of the prepared composites and the influence of irradiation dose on it have been studied as: compression strength, hardness, thermal decomposition temperature in nitrogen or oxygen, and the change in weight in aqueous solutions with different pH values. The glass transition temperature of the pure polymer and the composites increases with increasing the irradiation dose up to a plateau, and the glass transition temperature of the pure polymer is lower than that of the composites. The irradiation dose does not seem to affect the decomposition temperature of the pure polymer or the composites significantly and the decomposition temperature in presence of nitrogen is higher than that in presence of oxygen. Increasing the irradiation dose leads to an enhancement of the compression strength of the pure polymer and the prepared composites; the hardness of the pure polymer and the composites seems to be constant versus the irradiation dose. Soaking experiments show that the weight of composites does not change in distilled and alkaline medium, but there is a limited decrease in acidic medium of about 3% after 1560 h.
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