Abstract
Lipase PS catalyzes the enantioselective hydrolysis of various2-acetyl compounds of the 1- O-alkyl-3- O-arylsulfonyl- SN-glycerolderivatives to afford the corresponding optically active compounds.Changing the structure of the 1- O-alkyland 3- O-arylsulfonyl groups affects boththe reactivity and enantioselectivity. Finally, the E value of the reaction for 2-acetyl-3- O-3,5-dimethylbenzenesulfonyl-1- O-4-methoxybenzyl- SN-glycerolis greater than 200.
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