Abstract
The preparation of novel titanium complexes bearing o-phosphinophenol ligands is reported. The feature of this ligand system is that its electronic and steric properties can be independently tuned. The complexes were found to be fluxional by 1H NMR analysis at low temperature. An X-ray structural analysis showed that in the solid state the molecule is chiral at the metal center. These complexes were shown to be effective catalysts for olefin hydrogenation and imine hydrosilylation.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
