Preparation of Novel Nitrogen-Rich Fluorinated Hyperbranched Poly(amide-imide) and Evaluation of Its Electrochromic Properties and Iodine Adsorption Behavior.

Abstract

In this study, we successfully synthesized a novel triacid monomer by means of the thermal cyclization reaction. Subsequently, a series of nitrogen-rich (A3+B2)-type fluorinated hyperbranched poly(amide-imide)s (denoted as PAI-1 and -2, respectively) were prepared by means of a one-pot method using this triacid monomer and a diamine monomer with a triphenylamine-carbazole unit as precursors. The degree of support of the prepared hyperbranched PAIs was found to be about 60% via 1H NMR calculations. Through X-ray photoelectron spectroscopy (XPS), it was found that the binding energies of C-N (398.4 eV) and -NH (399.7 eV) became lower under a current, while the binding energy peak of N+ appeared at 402.9 eV. In addition, the PAIs have good solubility and thermal stability (Tgs: 256-261 °C, T10%: 564-608 °C). Cyclic voltammetry (CV) analysis shows that the hyperbranched PAI films have good redox properties, and a range of values for the HOMO (4.83 to 4.85 eV) versus LUMO (1.85 to 1.97 eV) energy levels are calculated. The PAI films have excellent electrochromic properties: PAI-1 on coloration efficiency (CE) and transmittance change (ΔT, 852 nm) are 257 cm2/C and 62%, respectively, and have long-lasting redox properties (100 cycles). In addition, we conduct iodine adsorption tests using the structural features of PAIs with electron-drawing units, and the results show that PAI-1 had a high adsorption capacity for iodine (633 mg/g).