Preparation of NiMoO4/CdS and its Application as a Photocatalyst in H2 Evolution Reaction

Abstract

AbstractThe construction of heterojunction is considered to be an effective strategy for achieving efficient photocatalyst. The pure CdS shows low hydrogen production activity, for the low charges separation efficiency and the short electron and hole lifetime, which greatly limit its practical application. Therefore, we constructed heterojunction photocatalysts of NiMoO4/CdS by a simple solvothermal method. The photocatalytic hydrogen production activity of CdS was obviously improved by NiMoO4 loaded. The NiMoO4/CdS‐2 sample shows the highest H2 generation rate, which could reach 5830.49 μmolg−1 h−1, which is 122.3 times higher than that of pure CdS. The construction of heterojunction between CdS and NiMoO4 inhibits the recombination of photogenerated charges, prolongs the lifetime of photogenerated charges and improves photocatalytic hydrogen production performance. This work is important for the construction of an efficient catalytic system for the photocatalytic H2 evolution from water splitting.