Abstract
Treatment of (1,1,3,3-tetramethyl)butyl isocyanide with one equivalent of alkyllithium reagent followed by one equivalent of chlorotrialkylstannane afforded 1,1,3,3-tetramethyl- N-[1-(trialkylstannyl)alkylidene]butanamines in good yields. Similarly, the reaction of 2,6-dimethylphenyl isocyanide with one equivalent of diethylzinc then with one equivalent of chlorotrimethylstannane gave 2,6-dimethyl- N-[1-(trimethylstannyl)-propylidene]benzenamine.
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