Abstract
Abstract The N-doped visible-light response nanosize TiO2 photocatalyst was prepared using the acid-catalyzed hydrolysis method followed by calcination in an NH3/N2 atmosphere. The photocatalytic activity of the prepared N-doped TiO2 for phenol degradation was investigated under visible and UV light irradiation. X-ray diffraction, UV-Vis diffuse reflectance spectroscopy, Fourier transform infrared spectroscopy, scanning electron microscopy, and N2 adsorption were used to characterize the catalyst. The results showed that the N-doped TiO2 catalyst displayed obvious photocatalytic activity under visible light irradiation. The N-doped TiO2 catalyst calcined at 500°C for 5 h exhibited the highest activity in both UV and visible light regions. N doping showed little effect on the crystalline structure, surface area, and crystal size of TiO2. The Ti O N bond formed on the surface of the catalyst extended the absorption edge to the visible light region (490–550 nm) and promoted the photocatalytic activity of TiO2 under UV irradiation. The newly formed Ti O N bonds and the reduced agglomeration of the single crystals were mainly responsible for the high activity of the N-doped TiO2 in both UV and visible light regions.
Published Version
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
