Preparation of nanosilica reinforced waterborne silylated polyether adhesive with high shear strength

Abstract

AbstractWaterborne adhesives are extremely environment‐friendly but unfortunately deficient in mechanical properties. In this article, nanosilica, stemming from tetraethyl orthosilicate (TEOS), silica sol, and/or fumed silica powder, was employed to reinforce the waterborne silylated polyether adhesives. Effects of TEOS content, silica sol content, and the type and content of fumed silica on the shear strength of the adhesive were investigated using a scanning electronic microscope and an electronic instron tester and the strengthening mechanisms of different silica source were discussed. All the shear strengths of silylated polyether adhesives first increased and then decreased as TEOS content, silica sol content or fumed silica content increased. Colloidal silica particles was less efficient than fumed silica particles for reinforcing the polyether adhesive but can increase the shear strength of hydrophobic fumed silica embedded adhesive. Comparing the adhesives with the hydrophilic fumed silica (HS‐5) or the extremely hydrophobic fumed silica (TS‐720), the adhesive with moderate hydrophobic fumed silica (TS‐610) had the highest shear strength. The maximal shear strength of 2.5 MPa was achieved when TEOS, silica sol, and fumed silica were combined. It seemed that TEOS, silica sol, and fumed silica played crosslinking (with polyether chain), dispersing (for fumed silica), and reinforcing roles on waterborne adhesive, respectively. This reinforcing mechanism opened a new way to fabricate waterborne adhesives (or coatings) with high performances. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008