Abstract
A kind of nanometric CeO 2–ZrO 2–Nd 2O 3 (CZN) solid solution for a carrier in the automotive three-way catalysts was synthesized by a coprecipitation method and characterized by means of X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), nitrogen adsorption–desorption (BET), scanning electron microscopy (SEM) and oxygen storage capacity (OSC). For the purpose of comparison, an unincorporated CeO 2–ZrO 2 (CZ) was also synthesized. The XRD measurements disclose the prepared CeO 2–ZrO 2–Nd 2O 3 have a face-centered cubic fluorite structure and nanoparticle sizes. According to the results of XPS, Nd 3+ ions can enter the CZ lattice and form a homogenous solid solution. Oxygen storage capacity measurements reveal that CeO 2–ZrO 2–Nd 2O 3 display high oxygen mobility at a low temperature. The results of the activity tests show that the catalyst exhibits good three-way catalytic activity and fairly wide range of air-to-fuel ratios.
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