Preparation of nanofiber core-spun yarn based on cellulose nanowhiskers/quaternary ammonium salts nanocomposites for efficient and durable antibacterial textiles

Abstract

Antibacterial fabrics are critical for the prevention of illness. Herein, we present a strategy for the preparation of a novel efficient and durable antibacterial nanofiber core-spun yarn (NCY) and antibacterial textile based on cellulose nanowhiskers (CNWs)/quaternary ammonium salts (QASs) composites for addressing the problems of easy shedding of antibacterial agents, unstable antibacterial effect, and triggering bacterial resistance in traditional antibacterial textiles. Through a facile coupling procedure, QAS and CNW are synthesized as CNW-QAS, which is a stable nanocomposite antibacterial agent. Based on a conjugated electrospinning device, CNW-QASs are firmly immobilized on the CNW-QAS/polyacrylonitrile (PAN) nanofiber shell layer by combining in situ doping with co-spinning to construct CNW-QAS/PAN NCY with efficient, fast and durable antibacterial properties. Its antibacterial rates against E. coli and S. aureus are both 99.99% even after multiple washes and long-term storage. In addition, the antibacterial yarn possesses a stress of 42.25 MPa and strain of 96.08%, providing excellent mechanical properties and flexibility. The exceptional performance makes CNW-QAS/PAN NCY a promising candidate for next generation antibacterial textiles.