Preparation of nanocrystalline SrTiO3 powder by sol–gel combustion method

Abstract

Abstract In this research a sol–gel combustion route has been presented to synthesize strontium titanate (SrTiO 3 :ST) nanocrystalline, using citric acid as fuel. The synthesis procedure was optimized by systematically varying the molar ratios of total metal nitrate to citric acid (MN:CA) from 1:1 to 1:3. The effect was investigated through XRD, SEM and TEM analysis. Analysis of XRD spectrum shows the complete of SrTiO 3 nanocrystalline, however, a minor phase of SrCO 3 impurity was found. Hence, an acid treatment process, with 1 mol/l HNO 3 solution and deionized water, was applied to remove the impurity. The results show that the appropriate condition to prepare the single phase nanocrystalline SrTiO 3 powders is MN:CA molar ratio of 1:3, coupled with an acid treatment process and at the lower calcination temperature of 500 °C. The particle size of powders was in nanometer ranges. The average crystallite size calculated from FWHM was about 23 nm. Morphology of powders was identified by SEM analysis. However, TEM estimated the average particle size about 7.5 nm after applying an acid treatment technique at 600 °C.