Preparation of multilayered C–Si–Al2O3 coatings on continuous carbon fibers and C–Si–Al2O3-coated carbon-fiber-reinforced hydroxyapatite composites

Abstract

Multilayered C–Si–Al coatings with various morphologies were deposited on carbon fibers (CFs) using magnetron sputtering. The thickness of the coatings was increased from 0.5 to 1.5 μm by magnetron sputtering between 90 and 120 min. C–Si–Al coatings of suitable thickness were heat-treated at 600 °C and transformed into C–Si–Al2O3 coatings by one-step anodic oxidation (AO). The oxidation time for the one/two-step anodic oxidation and the ratio of oxidation time for the two-step anodic oxidation significantly influenced the morphologies of the C–Si–Al2O3(AO) coatings. Al2O3 coatings with satisfactory morphologies and structures were prepared by two-step anodic oxidation with a total time of 30 min and a ratio of 1:1 between the initial and secondary oxidation times. The multilayered C–Si–Al2O3(AO) coatings were modified to C–Si–Al2O3 coatings by secondary heat treatment at 1050 °C. Subsequently, hot-press sintering was used to prepare CFs with multilayered C–Si–Al2O3 coating-reinforced hydroxyapatite (CF/C–Si–Al2O3/HA) composites. The multilayered C–Si–Al2O3-coated CFs demonstrated good resistance to oxidation and thermal shock. This could effectively protect CFs from oxidative damage and maintain its strengthening effect during sintering. The multilayered C, Si, and Al2O3 coatings effectively reduced the difference between the coefficient of thermal expansion of the CFs and HA matrixes. The interfacial gaps between the multilayered coatings and HA were reduced. This could enhance the mechanical performance of the composites. The CF/C–Si–Al2O3/HA composites exhibited improved mechanical properties with a bending strength of 83.94 ± 12.29 MPa, and fracture toughness of 2.45 ± 0.08 MPa m1/2. This study can broaden the application of CF/C–Si–Al2O3/HA biocomposites as bone-repair materials and help obtain CF-reinforced composites with excellent mechanical properties that are fabricated or serviced at high temperatures.