Abstract
In this work, a porous and honeycomb-structured Cellulose/Poly (vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) membrane is prepared via a facile and ecofriendly phase inversion method by using glycerol as pore forming agent. Cellulose acetate, the source of cellulose, is easily converted into cellulose by hydrolysis in the presence of lithium hydroxide. Owing to the unique microstructure, the Cellulose/PVDF-HFP membrane offers several advantages, including high porosity, elevated electrolyte uptake, high ion conductivity, and wide electrochemical window (5.35 V). Compared with conventional polypropylene (PP) separator and PVDF-HFP membrane, the membrane developed in this work enables higher discharge capacity, higher lithium-ion transference number (0.89) and improved rate performance, which is able to maintain a high discharge capacity of 136 mAh g−1 at 8 C, using LiCoO2 as cathode and Li metal as anode. In addition, the Cellulose/PVDF-HFP membrane based batteries exhibit superior cycling performance that can maintain 91.7% capacity after 100 cycles at 0.2 C. The characterization and battery test results demonstrate that the membrane is highly compatible with lithium ion batteries.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
