Preparation of mesoporous geopolymer using metakaolin and rice husk ash as synthesis precursors and its use as potential adsorbent to remove organic dye from aqueous solutions

Abstract

In this work, mesoporous geopolymer was synthesized using a novel and easy synthesis route employing metakaolin and rice husk ash as sources of silica and alumina, and soybean oil as a mesostructure-directing agent. For comparison purposes, a geopolymer sample was produced without the use of oil. The samples were characterized by Fourier transform infrared spectroscopy (FT–IR), X–ray diffraction (XRD), specific surface area, pore volume, average pore size, and pore size distribution (BET and BJH methods). The materials were tested to remove methyl violet 10B dye from aqueous solutions. The results showed that the mesoporous geopolymer presented adsorptive superior behavior compared to the geopolymer prepared without the use of oil, being attributed to its superior pore properties. The adsorption equilibrium was attained within 120min, and the maximum adsorption capacity of mesoporous geopolymer was 276.9mgg–1. Therefore, the mesoporous geopolymer prepared in this work comprises a potential adsorbent, presenting pore intrinsic properties that result in a high adsorption capacity.