Preparation of Magnetic Ni0.5Zn0.5Fe₂O₄/ZnO Nanocomposites and Their Photocatalytic Performances for Methylene Blue in Aqueous Solution.

Abstract

Magnetic Ni0.5Zn0.5Fe₂O₄/ZnO-R (NZFO/ZnO-R) nanocomposites are prepared via the rapid combustion-coprecipitation process, and they are characterized by the Fourier Transform Infrared Spectroscopy (FTIR), the X-ray Diffraction (XRD), the Scanning Electron Microscopy (SEM), the Energy Dispersive X-ray Detector (EDX), the Specific Surface Area (BET), the UV-vis Diffuse Reflection Spectroscopy (DRS), and the Vibrating Sample Magnetometer (VSM). The photocatalytic activity of NZFO/ZnO-R nanocomposites is assessed in ultraviolet light (365 nm) by decoloration of methylene blue (MB). The results show that the magnetic NZFO/ZnO-0.2 nanocomposites consist of particles and rods. The size of particles is 18 nm. The width and length of rods are 66 nm and 198 nm, respectively. NZFO/ZnO-0.5 nanocomposites have better photocatalytic performance than that of NZFO, ZnO and NZFO/ZnO-R (R = 0.2, 0.3, 0.4, 0.6, or 0.7) from the results. Through careful investigation of influencing parameters (the amount of catalysts, pH and concentration of MB solution), the degradation efficiency of MB is closely connected with the transparency of solution and surface charge of catalysts. The enhanced photocatalytic activity of NZFO/ZnO-0.5 nanocomposites can be ascribed to the matching band positions between ZnO and NZFO, which results in a low recombination between the photogenerated electron-hole pairs. The possible mechanism is proposed for the improved ultraviolet photocatalytic activity of NZFO/ZnO-0.5 nanocomposites.