Preparation of Macroporous Lime from Natural Lime by Swelling Method with Acetic Acid for High-Temperature Desulfurization

Abstract

To develop a highly active calcium oxide high-temperature desulfurization sorbent, a method of preparation of macroporous calcium oxides from lime was studied. This method is composed of two steps: swelling of the lime and calcination of the swelled sample. Swelling occurred when lime was exposed to the vapor of acetic acid. The swelling resulted from calcium acetate formation in the sample. The swelling rate was at a maximum in the presence of acetic acid and depressed by the presence of water vapor. The swelled sample was converted to macroporous calcium oxide by heating to 850 °C. The reactivity of the macroporous calcium oxide for the removal of SO2 or H2S in the presence of H2O vapor was higher than that of the calcined raw limestone. In particular, its SO2 removal capacity and the oxidative character of CaS to CaSO4 and CaO were greatly improved by this swelling method. These characteristics were also compared with those of a sample prepared from limestone by this swelling method.