Abstract

Polymeric lanthanide complexes have been synthesized through ring-opening metathesis polymerization of monomeric lanthanide complexes of pyridine dicarboxylates that contain a norbornene group. The lanthanide monomer complexes, Eu(III) and Tb(III) complexes, have three norbornene groups that allow three-dimensional polymeric networking, and the corresponding polymers of Eu(III), Tb(III), and their equimolar complexes are highly luminescent with intense emission bands in the characteristic visible region.

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