Abstract
Soluble π-conjugated coordination polymers having a ruthenium(II) complex in the main chain were prepared from a “soluble metal complex monomer” and a “bridging ligand” via coordination. Refluxing of an ethanol-water suspension containing (4,4′-dinonyl-2,2′-bipyridyl)Ru(III) with 2,3-bis(2′-pyridyl)pyrazine gave the coordination polymer. The resulting polymer was soluble in common organic solvents. The structure was confirmed by uv/vis spectra and gpc analysis.
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