Abstract
Abstract Hybrids possessing both oligomeric ethylene oxide chains and Ti–O–P networks were prepared from TiCl4 and organodiphosphonic acid [(HO)2OP(C2H4O)3C2H4PO(OH)2] via a nonhydrolytic sol–gel process and subsequently treated with a LiClO4 solution. The P/Ti ratio was fixed at 2 and the ethylene oxide unit/Li+ ratio was changed from 5 to 20. Li+ ions are likely to be solvated by ether oxygen atoms. Li+ ion transport in the hybrids with ionic conductivity values in the 10−5 S cm−1 range was observed at ambient temperatures.
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