Preparation of lanthanum trifluoride nanoparticles surface-capped by tributyl phosphate and evaluation of their tribological properties as lubricant additive in liquid paraffin

Abstract

LaF3 nanoparticles surface-capped by tributyl phosphate (denoted as TBP–LaF3) were prepared by in situ surface modification route. The size, morphology and phase structure of as-prepared TBP–LaF3 nanoparticles were analyzed by means of X-ray diffraction and transmission electron microscopy. The thermal stability of as-synthesized TBP–LaF3 nanoparticles was evaluated based on thermogravimetric analysis, and their tribological properties as additive in liquid paraffin were evaluated with a four-ball friction and wear tester. Moreover, the morphology of worn steel surfaces was analyzed with a scanning electron microscope, and the composition and chemical state of typical elements on worn steel surfaces were examined with an X-ray photoelectron spectroscope. Results show that as-synthesized TBP–LaF3 nanoparticles possess good thermal stability and excellent anti-wear and load-carrying capacities as well as good friction-reducing ability. This is because, on the one hand, TBP as the surface-modifier is able to improve the dispersibility of LaF3 nanoparticles in liquid paraffin and allows good adsorption of LaF3 nanoparticles on sliding steel surfaces. On the other hand, active P element of TBP can form tribochemical reaction film on sliding steel surfaces. As a result, the boundary lubricating film consisting of adsorbed LaF3 nanoparticles and tribochemical reaction film results in greatly improved friction-reducing and anti-wear abilities as well as load-carrying capacity of the lubricant base stock and gives rise to significantly reduced friction and wear of the steel–steel sliding pair.