Abstract
Hydrido-diene complexes of general formula IrH(diene)L 2 (diene = tetrafluorobenzobarrelene (TFB), 1,5-cyclooctadiene (COD); L = PPh 3; L 2 = bis(1,2-diphenylphosphino)ethane (dppe), bis(1,3-diphenylphosphino)propane (dppp)) have been obtained by decomposition of methoxyiridium complexes. The related IrH(diene)(AsPh 3) 2 complexes have been prepared from iridium chloro-diene compounds. The catalytic activity of IrH(COD)L 2 complexes in hydrogen transfer reactions from alcohols to cyclohexanone is described.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
