Preparation of HMn2O4 lithium-ion sieves with low manganese dissolution loss for improved cycling stability.

Abstract

Manganese-based lithium-ion sieves have become some of the promising adsorbents for extracting Li+ from brines. However, manganese dissolution loss (MDL) severely impairs the stability and cyclicity of ion sieves. A novel ozone eluent was first developed to extract Li+ from lithium manganese oxides, which decreased MDL decreased from 5.89% to 0.11%, and after ten regeneration cycles, the adsorption capacity retained 85.39% of the initial value, which was better than 55.15% when only hydrochloric acid (HCl) was used as the eluent. Based on these phenomena, the mechanism for the O3 lowering of MDL was investigated. First, the catalytic decomposition reaction of O3 competed with the disproportionation reaction, and the involvement of O3 inhibited the occurrence of the disproportionation reaction. Additionally, the presence of O3 and reactive oxygen species provided a preferential electron acceptor compared to Mn3+ during the migration of electrons from the bulk phase to the surface. In this study, MDL was greatly reduced with a very simple strategy, and the cycling stability of the adsorbent was improved.