Abstract
A series of novel stable polyurethane emulsion with high-solid-content and low-viscosity were prepared by self-emulsification. They were prepared by the reaction of poly (tetrahydrofuran-co-oxidation of propylene) glycol (Ng210), isophorone isocyanate (IPDI) with 1,2-dihydroxy-3-propanesulfonic acid salt (DHPA) as hydrophilic chain-extending agents. Influence of the content of DHPA on properties of polyurethane emulsion and film were analyzed .The results show that obtained emulsion were multivariate distribution in particle size and were spherical particles by measurement of grain size and electron microscopic photo. It is noticed that with increasing content of DHPA and, average particles diameter of polyurethane emulsion became smaller, poly-dispersion became narrower and solid-content became bigger. when the content of DHPA is 7%, solide-concent of emulsion reaches 61%. In addition, Polyurethane emulsion are endowed stability of emulsion are good at high temperature and low temperature as well as storage stability.
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