Abstract

Cu films were deposited on Si(1 0 0) substrates by applying a negative substrate bias voltage using non-mass separated ion beam deposition (IBD) method. By the SIMS results with Cs + ion beam, the Cu film deposited at V S=0 V was found to contain more impurities than the Cu film deposited at V S=−50 V. On the other hand, from the SIMS results with O 2 + ion beam, it was found that elements which are easy to be positive ions such as B, Mg, Na, Al, K, Ca and Fe seem to be increased slightly as compared to the those of the Cu film deposited at V S=0 V. As a result, higher-purity Cu film deposited at V S=−50 V could be obtained in comparison with the film deposited at V S=0 V. The purification effect of the Cu film deposited at V S=−50 V was described in details.

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