Preparation of helical TiO2/CMC microtubes and pure helical TiO2microtubes

Abstract

Helical TiO2/CMC (carbon microcoils) microtubes and helical TiO2 microtubes were obtained by making TiO2 layer coatings on the surface of CMC templates using a sol-gel and chemical vapor deposition (CVD) processes. The preparation conditions, morphologies and some properties were examined. Uniform TiO2 (anatase) layers were obtained on the CMC templates by a CVD process using vapor phase hydrolysis of titanium tetra-isopropoxide at 300°C followed by heat treatment in N2 or by calcination in air at 500–;650°C. The helical TiO2/CMC microtubes showed good photocatalytic activity. It was considered that the helical structure activated and enhanced the photocatalytic activity of TiO2, probably caused by the generation of inductive microelectric current induced by the irradiation of UV light, resulting in the generation of micromagnetic fields around the tubes.