Abstract

The simultaneous graft copolymerization between natural rubber (NR) and styrene monomer (St) was induced by electron beam irradiation. The grafted polystyrene in graft copolymer was characterized by Fourier Transform Infrared Spectroscopy (FT-IR). This research investigated the influence of three factors (radiation dose, type of emulsifier and adding of sensitizer; normal butyl acrylate (n-BA)). It was found that the appropriated emulsifier was ammonium laurate which lead to higher monomer conversion and grafting efficiency. The adding of n-BA could notably enhance monomer conversion and crosslink density. Moreover increasing radiation dose, the monomer conversion and crosslink density increased. This technique was a cleaner and faster technology suitable for grafting application.

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