Abstract

AbstractFluorescent nanocapsules containing Eu3+ complex are prepared by the internal phase separation of poly(methylmethacrylate) (PMMA) within the droplets of oil/water nano-emulsion. The nanocapsules give bright red emission excited by UV irradiation and possess stable fluorescence properties. Their fluorescence intensity is primarily influenced by the emulsifier concentration. It is significant that the fluorescence of the nanocapsules is nearly pH-independent and can be kept for a long time in a wide pH range. In contrast, the fluorescence of Eu3+ complex is easily quenched in acidic or alkalic medium. The mean nanocapsule size is tunable with the concentration and the mode of emulsifier addition. As soft templates, oil cores have potential applications for the incorporation of functional components or drugs.

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