Preparation of fibrous ceramic-based catalytic membranes by microwave heating and their structural properties and dust and NO removal characteristics

Abstract

Different drying methods were used to prepare catalytic membranes for the simultaneous removal of dust and NO to explore their effect on the distribution of active components, with the structural properties, filtration performance, catalytic performance, and working mechanism of the preferred prepared catalytic membrane systematically investigated. The results indicated that microwave drying, in contrast to traditional electric drying with blasting, effectively inhibited the migration of the precursor solution to achieve uniform loading of active components, thus endowing the catalytic membrane with excellent catalytic activity. Meanwhile, the pore structure of the fibrous ceramic substrate was not almost affected by the loaded catalyst and still exhibited high porosity. These characteristics contributed to the development of a catalytic membrane with good filtration and catalytic performance, as well as superior adaptable NO concentration and filtration velocity properties. Therefore, fibrous ceramic-based catalytic membranes prepared using microwave assistance offer considerable application prospects for integrated purification of high-temperature flue gases. Furthermore, the removal of dust and NO was determined to follow the Eley–Rideal reaction mechanism and surface filtration mechanism of the residual dust cake, respectively.