Preparation of fast-swelling porous superabsorbent hydrogels with high saline water absorbency under pressure by foaming and post surface crosslinking

Abstract

Superabsorbent hydrogels have wide applications in many fields because of their unique water absorbing performance. In spite of decades of research about superabsorbent hydrogels, high water absorbency under pressure and fast-swelling are still challenging and highly desired for their applications in hygienic products and others. Here, we report preparation of fast-swelling porous starch-g-poly(acrylic acid)/poly(vinyl alcohol) superabsorbent hydrogels with high saline water absorbency under pressure by foaming and post surface crosslinking. 2,2′-Azobis(2-amidinopropane) dihydrochloride (AIBA) was used as a new porogen instead of conventional porogens like NaHCO3. Post surface crosslinking of the hydrogel was achieved using glycerol via the esterification reaction. AIBA is a better porogen than NaHCO3 regarding porosity and swelling performance of the hydrogels, and its content has great influences on structure and swelling performance of the hydrogels including water absorbency and swelling rate. Also, the surface crosslinking using glycerol can significantly enhance the saline water absorbency under pressure (2 kPa) but at the sacrifice of the swelling rate. Consequently, the hydrogels show high water absorbencies for deionized water (560 g/g), 0.9 wt% NaCl solution (58 g/g), 0.9 wt% NaCl solution under 2 kPa pressure (28 g/g) and fast-swelling (31 s to achieve a highly swelling state).